Enantiomeric disorder in racemic cis-dichlorobis(pentane-2,4-dionato)titanium(IV).
نویسندگان
چکیده
The title compound, [Ti(C(5)H(7)O(2))(2)Cl(2)], adopts the cis configuration. The racemic compound crystallizes in space group P1 and each molecular site has 0.50 occupancy by each of the two enantiomorphs. The enantiomeric disorder is correlated in two dimensions.
منابع مشابه
A 2:1 cocrystal of the cis and trans isomers of bis[1,1,1,5,5,5-hexafluoropentane-2,4-dionato(1−)-κ2 O,O′]bis(4-phenylpyridine N-oxide-κO)copper(II)
The title compound is a co-crystal of the cis and trans isomers, namely cis-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis-(4-phenyl-pyridine N-oxide-κO)copper(II)-trans-bis-[1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato(1-)-κ(2)O,O']bis(4-phenyl-pyridine N-oxide-κO)copper(II) (2/1), [Cu(C(5)HF(6)O(2))(2)(C(11)H(9)NO)(2)]. In both isomers, the coordination geometry of the Cu(2+...
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The title complex, [Co(2)(C(5)HF(6)O(2))(2)(C(5)H(7)O(2))(2)(H(2)O)(2)], is centrosymmetric with a crystallographic inversion center in the middle of the mol-ecule. The octa-hedrally coordinated Co(II) atoms are bridged by two chelating acetyl-acetonate (acac) ligands and two more electron-poor 1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato (hfac) ligands are bonded terminally in a solely chelatin...
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ورودعنوان ژورنال:
- Acta crystallographica. Section C, Crystal structure communications
دوره 57 Pt 3 شماره
صفحات -
تاریخ انتشار 2001